hehe, should have more faith in soft yeah. Capcitor is a very basic component, but when in the hand of "mojoed" geetar players, suddenly there be lotsa majik which prolly will make music more beautiful.
Guitar usage aside, here is prolly more than enough info to make geetarers give up trying to find out different kind of capacitors, still, it is all about capacitors.
http://en.wikipedia.org/wiki/Capacitor
If anyone wanna for the fun of it, can just pop in those polarised cap just for the fun of it and see how it affect the sound. I have only tried it on effect circuit(interchanging polarised cap with non polarised type) so cant really say how it affect geetar sound in the tone pot section. But if you wanna try it on geetar, theres no harm done. There is prolly no danger of anysort in a guitar circuit,
generally.
On the tone control, with just a capacitor alone, it doesnt work towards the purpose of rolling off the highs (frequency). It need to work hand in hand together with the value of the tone potentiometer, taper response etc to make a difference
using a cheap ceramic cap(which some geetars used to have as factory default) compare to all those fancy caps on top of the different value pots, theres prolly differences. Theres difference in the roll off response, aka improved fidelity/tone balance when rolling off the tone pot without getting mushy tone too fast, too furious and perhaps a slight/tiny improvement on the sound when tone pot is set to full. The effect of the cap will only have most effect when you adjust the tone pot, as thats where the filtering take place.
Oh yeah, if anyone able to record clips of the differences in sound a cap change will do, best! Even better still, if able to capture a screen shot of different caps in action, with the signal fed through a spectrum analyser. The differences can be seen and not just heard, which in the first place, varies among us.